Sep 20, 2019 Pageview:848
Dry battery belongs to the galvanic battery in the chemical power supply, it is a kind of disposable battery, it thinks carbon rod is positive pole, with zinc canister is negative pole, change chemical energy into electric energy to supply external circuit. In the chemical reaction, because zinc is more active than manganese, zinc loses electrons to be oxidized and manganese gains electrons to be reduced.
Ordinary dry-cell batteries are mostly zinc manganese battery, the middle one is the anode carbon rod, a mixture of graphite and manganese dioxide of outsourcing, the outside is a layer of mat again. Online electrolyte with very thick paste, its composition is the ammonium chloride solution and starch, and small amounts of preservatives. The outermost layer is made of metal zinc skin tube, which is negative, the battery discharge is the ammonia chloride and zinc electrolytic reaction, release the charge by graphite conductive to the anode carbon, zinc electrolysis reaction is will release hydrogen, this gas is may increase the risk of battery internal resistance, and mixed with graphite manganese dioxide is used to absorb hydrogen. But if the work continuously or the battery is too long, manganese dioxide is too late However, if the battery is heated or left for a period of time, the accumulated hydrogen inside will be released by heat or slowly.
Schematic diagram of working principle of battery
The basic components of a battery are the anode, cathode, and electrolyte
Anode: electrons are removed through an external circuit and the electrode itself is oxidized. Cathode: electrons are obtained through an external circuit, and the electrode itself undergoes a reduction reaction.
Electrolyte: provides a migration channel for ions from one electrode to another within the cell.
The active material of the electrode can be gas, liquid or solid, and the electrolyte can be liquid or solid.
Alkaline battery
The cathode reaction
Zn+2OH-->ZnO+H2O+2e-
The positive response
2MnO2+H2O+2e-->Mn2O3+2OH-
Complete response
Zn+2MnO2->ZnO+Mn2O31.5V
2. Lithium thionyl chloride battery
The cathode reaction
Li->Li++e-
The positive response
4Li++4e-+2SOCl2->4LiCl+SO2+S
Complete response
4Li+2SOCl2->4LiCl+SO2+S3.6V
3.Lithium manganese dioxide battery
The cathode reaction
Li->Li++e
The positive response
MnO2+Li++e->MnIIIO2(Li+)
Complete response
Li+MnO2->MnIIIO2(Li+)3.6V
4. Nimh batteries
The cathode reaction
MH+OH-<->M+H2O+e-
0.83V
The positive response
NiOOH+H2O+e-<->Ni(OH)2+OH-
0.49V
Complete response
NiOOH+MH<->Ni(OH)2+M
1.32V
5. Nickel cadmium battery
The cathode reaction
Cd+2OH-<->Cd(OH)2+2e-
0.81V
The positive response
NiOOH+2H2O+2e-<->Ni(OH)2+2OH-
0.49V
Complete response
Cd+NiO2+2H2O<->Cd(OH)2+Ni(OH)2
1.30V
6. Lithium ion battery
The cathode reaction
6C+Li++e-<->6CLi
The positive response
LiCoO2<->CoO2+Li++e-
Complete response
6C+LiCoO2<->CoO2+6CLi
3.7V
7. Lithium polymer battery
The cathode reaction
6C+Li++e-<->6CLi
The positive response
LiCoO2<->CoO2+Li++e-
Complete response
6C+LiCoO2<->CoO2+6CLi
3.7V
8. Nickel zinc battery
The cathode reaction
Zn+2OH-<->Zn(OH)2+2e
1.24V
The positive response
NiOOH+2H2O+2e-<->Ni(OH)2+2OH-
Complete response
2NiOOH+Zn+2H2O<->2Ni(OH)2+Zn(OH)2
1.73V
9. Sodium sulfur battery
The cathode reaction
2Na<->2Na++2e-
The positive response
3S+2e-<->S32-
Complete response
2Na+3S<->Na2S3
2.076V
10. Iron nickel battery
The cathode reaction
Fe+2OH-<->Fe(OH)2+2e-
3Fe(OH)2+2OH-<->Fe3O4+4H2O+2e-
0.81V
The positive response
2NiOOH+2H2O<->2Ni(OH)2+2OH-
0.49V
Complete response
3Fe+8NiOOH+4H2O<->8Ni(OH)2+Fe3O4
1.30V
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