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Understanding the Reasons Behind the Reduction of Life and Capacity of Lithium Polymer Batteries

Jun 26, 2023   Pageview:328

Lithium polymer batteries have revolutionized the world of portable electronics, powering our smartphones, tablets, laptops, and other devices with their high energy density and lightweight design. 

However, users often encounter a common problem with these batteries—their life and capacity gradually diminish over time. Understanding the reasons behind this reduction is vital for both consumers and manufacturers in order to improve battery performance and extend their lifespan.

In this article, we will delve into the factors that contribute to the reduction of life and capacity in lithium polymer batteries. We will explore the intricate workings of these batteries, examining the various aspects that impact their overall performance. 

By shedding light on these factors, we aim to provide valuable insights into why lithium battery capacity decreases and how we can mitigate these issues.

From chemical degradation to cycle aging, there are several factors that play a role in the diminishing capacity of lithium polymer batteries. We will discuss the chemical reactions that occur during the charging and discharging process, leading to the degradation of the battery's electrode materials. 

We will also explore the impact of temperature fluctuations, overcharging, and deep discharging on the battery's performance, and how they accelerate the degradation process.

Moreover, this article will examine the concept of cycle life and how each charge and discharge cycle affects the capacity of lithium polymer batteries. We will highlight the importance of improving electrode materials and optimizing charging algorithms to extend the battery's cycle life.

Additionally, we will explore how impurities present in the battery's electrolyte can contribute to capacity reduction, causing the formation of solid deposits that impede ion flow and increase internal resistance.

By addressing these issues, users will gain valuable knowledge on how to maximize the life and capacity of their lithium polymer batteries. 

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We will provide practical insights into battery conditioning techniques, proper charging practices, and effective maintenance to optimize battery performance and extend their overall lifespan.

Now, let's delve deeper into the first topic and explore why lithium battery capacity decreases.

Why Does lithium battery Capacity Decrease?

Lithium polymer batteries have gained significant popularity in various electronic devices due to their high energy density, lightweight design, and long-lasting performance. 

However, over time, these batteries experience a reduction in their life and capacity, affecting their overall performance. 

In this article, we will explore the factors that contribute to the decrease in lithium battery capacity and provide insights into the underlying causes.

Battery capacity decrease can occur due to several reasons. One primary factor is the formation of a solid electrolyte interface (SEI) layer on the electrode surfaces. The SEI layer develops naturally as a result of the interaction between the electrolyte and electrode materials. 

While this layer is necessary for the battery's stability, its continuous growth can lead to a decrease in the available active electrode surface area, resulting in reduced capacity.

Another reason for capacity reduction is the occurrence of side reactions during charge and discharge cycles. 

These reactions can generate unwanted byproducts, such as metal dendrites or gas bubbles, which interfere with the battery's performance. Additionally, the accumulation of these byproducts can lead to internal short circuits or increased resistance within the battery, further contributing to capacity loss.

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Moreover, factors like high operating temperatures, overcharging, and deep discharging can accelerate the capacity degradation process. 

Elevated temperatures increase the rate of chemical reactions within the battery, causing faster deterioration of the electrode materials and electrolyte. Overcharging the battery leads to the deposition of lithium metal on the electrode, creating irreversible changes and reducing the overall capacity. 

Similarly, deep discharging can cause structural damage to the electrodes and compromise the battery's ability to store charge effectively.

Examining Failures in lithium-ion batteries

In recent years, there have been cases of lithium-ion battery failures that have garnered attention due to safety concerns. 

Understanding the reasons behind these failures is crucial to improving battery technology and ensuring safer usage. Let's explore some common failure modes in lithium-ion batteries.

One prominent failure mode is thermal runaway, which occurs when a battery experiences uncontrolled heating leading to an uncontrollable release of energy. 

Thermal runaway can result from external factors like physical damage, exposure to high temperatures, or internal issues within the battery. It can trigger a chain reaction, rapidly spreading to neighboring cells and potentially causing fires or explosions.

Another failure mode is electrolyte decomposition. The electrolyte in lithium-ion batteries is a critical component responsible for facilitating the movement of ions between the electrodes. 

However, under certain conditions, such as high voltage or elevated temperatures, the electrolyte can decompose, leading to the formation of highly reactive species. These species can react with the electrode materials, causing irreversible damage and capacity loss.

Furthermore, mechanical stresses can contribute to battery failures. Physical deformation or puncture can compromise the integrity of the battery's internal structure, leading to short circuits, electrolyte leakage, and potential thermal events. 

Battery manufacturers continually work on improving the mechanical robustness of lithium-ion batteries to minimize the risk of failures.

lithium-ion battery Life and Conditioning

Extending the life and optimizing the performance of lithium-ion batteries require proper conditioning and maintenance. Battery conditioning techniques play a crucial role in maximizing capacity and overall longevity.

One important practice is to avoid frequent deep discharges. While occasional deep cycling can recalibrate the battery's state of charge estimation, repeated deep discharges can strain the electrodes and accelerate capacity degradation. 

Instead, shallow and regular discharges, followed by appropriate charging, can help maintain a healthier battery.

Proper charging practices are also vital for battery longevity. Avoid overcharging or leaving the battery connected to a charger for an extended period. 

Modern lithium-ion batteries are equipped with advanced charging circuitry that helps prevent overcharging. However, it is still advisable to unplug the device once it reaches full charge to minimize stress on the battery.

Regular battery maintenance includes keeping the battery within the optimal temperature range. Exposing lithium-ion batteries to extreme temperatures, especially high temperatures, can significantly degrade their performance and shorten their lifespan. 

Additionally, storing the battery at full charge for extended periods can contribute to capacity loss, so it's advisable to store them at around 50% charge in a cool environment.

In conclusion, understanding the reasons behind the reduction of life and capacity of lithium polymer batteries is essential for users and manufacturers alike. 

By being aware of the factors contributing to capacity decrease, examining failures, and implementing proper battery conditioning techniques, users can maximize the lifespan and performance of their lithium-ion batteries. 

Additionally, continued research and technological advancements will further enhance the reliability and safety of these batteries, paving the way for future innovations in portable power storage.

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