Jan 10, 2019 Pageview:694
Safety performance analysis of cobalt acid lithium batteries, we will analyze by the nickel cobalt manganese acid lithium, lithium iron phosphate, and cobalt acid lithium manganese acid lithium battery on security in detail.
1, nickel cobalt manganese acid lithium (3) battery
On the practical theory than energy has greatly improved, relative to the and cobalt acid lithium battery, can better give play to the role of high capacity, but look from the material, The ternary battery using lithium nickel manganese cobalt acid and organic electrolyte, temporarily not fundamentally solve the problem of security, if the battery short-circuit speak too large current generated, causing potential safety problems.
2,lithium iron phosphate batteries
Theoretical capacity is 170 mAh/g, make material of the actual capacity of 160 mAh/g.On the security, high thermal stability, lithium iron phosphate electrolytic low melt oxidation ability, and high safety; But the defect is low conductivity, the volume is too large, the electrolyte dosage, due to the large capacity, poor consistency of battery.
3, cobalt acid lithium batteries
On the preparation of the biggest characteristic is that after a full charge, there are still a lot of lithium ions at the anode, that is, on the cathode hold more attached to the anode of lithium ion, but in the condition of overcharge, the positive to negative excess lithium ion will still be on swimming, because can't hold back on the cathode is formed on the metal lithium, because the metal lithium is dendritic crystal, thus known as dendrite, the dendrite once formed, will provide the opportunity to Pierce the diaphragm, diaphragm Pierce will form the internal short circuit. Due to the electrolyte composition are mainly carbonate, flash point and boiling point is low, in the case of higher temperature will burn even explode. Control the formation of lithium dendrite easy on small capacity lithium battery, so the cobalt acid lithium batteries currently limited to portable electronic devices such as small capacity battery, cannot be used power battery。
4, manganese acid lithium battery
Manganese acid lithium battery is a bit of material. It can make sure the full charge condition. The anode of lithium ion can be fully embedded in the cathode carbon holes, rather like cobalt acid lithium residue in the anode to a certain extent. It fundamentally avoids the production of dendrite in theory. In fact, if a strong external force works on manganese acid lithium battery or cut corners in the process of preparation, it may cause the battery lithium ions move rapidly in the process of charging and discharging cycle at the moment. In the case of lithium ion cathode is difficult to work quickly and become dendrite. To avoid the consequences, the battery factory test to ensure that. Anyhow, testing qualified manganese acid lithium battery does not generally lead to safety accidents occur, the structure of the manganese acid lithium solid performance is far lower than the cobalt acid lithium oxide. Even if the external short circuit, it can also avoid the precipitation of metal lithium due to combustion and explosion.
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